Responsive Polyelectrolyte Multilayers Assembled at High Ionic Strength with an Unusual Collapse at Low Ionic Strength

Responsive polyelectrolyte multilayers (PEMs) of poly(diallyl dimethyl ammonium chloride) (PDADMAC) and poly(styrene sodium sulfonate) (PSS) with thicknesses between 350 and 400 nm for 11 deposited polyelectrolyte layers were fabricated assembling the polyelectrolytes at 3 M NaCl. When the 3 M NaCl bulk solution is replaced by water, the PEMs release water, approximately a 46% of the total mass, and experience a thickness reduction of more than 200 nm. Changes in thickness and water content are fully reversible. The film recovers its original thickness and water content when it is exposed again to a 3 M NaCl solution. A responsive polymer film is achieved with the capability of swelling at high ionic strength and collapsing in water with variations in thickness of hundred of nanometers.     

基于ANN的定向井有杆抽油系统悬点示功图特征参数的计算

有杆抽油系统悬点示功图的特征参数是合理选择地面机电设备的主要依据.由于井下工况的复杂性和部分参数难以确定,使得基于求解高维时变非线性方程的传统方法的计算结果存在偏差.本文将传统方法和神经网络相结合,给出了一种能比较精确地确定定向井有杆抽油系统悬点示功图特征参数的方法,避免了建立和求解复杂的非线性动力学方程.首先依据传统方法,计算出简化悬点示功图的特征参数.然后考虑抽油杆柱弹性振动、抽油杆与油管之问的库仑和粘性摩擦、气体和供液能力等因素的影响,利用BP神经网络和RBF神经网络建立了不同工况下悬点示功图特征参数的计算模型.利用现场实测数据对建立的神经网络进行了训练和测试.测试结果表明了本文方法的正确性和有效性.     

实用智能卡操作系统的认证系统

阐述了一种实用的智能卡操作系统MAXCOS的认证系统,包括对持卡人的身份认证、卡与读写设备之间的认证、安全报文传送,对这几种认证机制进行了详细的阐述和分析．     

智能卡操作系统中RSA算法的实现与应用

讨论了RSA算法在IC卡中的应用,以及在Ic卡中实现RsA算法的一种途径,即利用中国剩余定理(cRT)来简化大数乘方取模运算．该方法在Ic卡芯片上已经成功实现．测试结果表明,在Ic卡中运用这种方法实现的RsA算法其解密速度与同等条件下的Des算法的加解密速度相当.     

High Pressure Induced Coil-Globule Transitions of Smart Polymers

Summary: In current work time-resolved optical spectroscopy (TROS) has been used to study coil-globule transitions monitored by the local segmental dynamics of anthracene labeled poly (N-isopropymethacrylamide), PNIPMAM as a function of pressure (0.1 MPa–200 MPa) over a temperature range of 283 K to 333 K. The positions of temperature-induced transition were observed to be independent on molecular weight of polymer at low pressures. The positions of pressure-induced transition were observed to be dependent on molecular weight of polymer at temperatures below LCST at atmospheric pressure. Double globule-coil-globule transition was observed to occur with pressure increasing at temperatures nearly above LCST. All these results along with values of intrinsic viscosity evaluated from values of correlation times measured for globules formed at different pressure/temperature conditions suggest the different mechanisms of compactisation governed by pressure and temperature and, correspondently, the different types of final structures. At low pressures with temperature increasing the compact, well-packed globules are forming via initial interactions between neighboring parts of polymer chain and further collapse. Relatively loosened particles are forming with pressurizing at low temperatures. Interaction between remote along the chain units takes part from the first stage of globule formation. And finally, rather solvated and irregularly twisted particles are forming at high pressure and high temperatures, i.e. at conditions, when both processes are involved.     

Hamilton等参元与智能叠层板的半解析法

根据压电材料修正后的Hellinger-Reissner(H-R)变分原理,建立了各向异性压电材料4节点Hamilton等参元的一般形式．为智能叠层板自由振动问题和带有压电块的叠层悬臂梁的瞬态响应等问题提出了一种新的半解析法．数学模型的基本步骤:将压电层和主体层看成独立的三维体,在平面内离散各层,分别建立各层的方程;根据主体层和压电层在连接界面上广义应力和广义位移的连续条件,联立主体层和压电层的方程得到全结构的控制方程．等参元不限制智能板侧面的几何边界形状、板的厚度和层数,有广泛的应用领域．     

A Simple Closed-Loop Active Control of Electrodynamic Shakers by Acceleration Power Spectral Density for Environmental Vibration Tests

This work presents the main results of a simple closed-loop active control for an electrodynamic shaker in order to generate acceleration Power Spectral Densities (PSD) according to prescribed Standards used in environmental vibration tests. The main idea is to start generating acceleration pseudo-signals obeying the prescribed Power Spectral Density and then to acquire acceleration data from the electrodynamic shaker’s table behaviour. So the Power Spectral Density of the acquired acceleration is computed and compared with the required PSD and then the time-varying pseudo-acceleration is updated to reflect this corrected PSD. It was noticed that for piecewise narrow bands frequencies, the electrodynamic shaker acceleration behaves near linearly, both in frequency and voltage, for the input signals. A code in AgilentVee 7.5 software to acquire, send and process signals for the active control in a closed-loop scheme was developed. The used A/D D/A hardware was a single PC sound card with specific characteristics. The control could be accomplished sending and acquiring at the same time with a range of input/output of ±1.5 V with 16 bits of resolution, at 48 kHz and assistance of an external sound amplifier.     

智能板模态传感与控制的数值分析

智能结构技术对空间大型柔性结构 振动控制问题具有重要意义,采用独立模态空间控制技术对压电智能板进行主动振动控制是一种常用方法,以前对这一问题的研究仅限于解析的方法,本文采用有限单元法,设计了新的压电模态传感器与致动器,该方法能够适用于形状及边界条件较为复杂的智能板,算例分析证明了该方法的正确性。     

含ER流体板结构的振动特性研究

本文制作了含电流变体夹层梁和模拟飞机蒙皮结构的含电流变体加筋层合板,采用响应幅频法,测试了在不同电场强度梁和层合加筋板结构各阶固有频率和振幅的变化;并着重测试了加筋层合板结构在改变板材料、电流变体作用面积等条件时各阶频响特性的变化。实验结果表明,随着电场强度的增加,夹层梁的频响特性有很大变化;而层合板的固有频率变化不大,但振幅却有显著变化,其中铝－层合加筋板的频响幅值的变化率达到５０．１％。     

复合材料层合板面内压阻效应层合理论研究

应用经典层合板理论和静电学理论,研究了正交异性介质的电导率,压导系数和压阻系数的特性,导出了Ｃａｕｃｈｙ应变空间中压阻系数与压导系之间的关系;建立了平面应力状态下层合板面内压阻效应的层合理论。